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| Visibility | public |
| Electrolyte | Anolyte (negative): 0.1–0.2 M RFP + 0.4–1.6 M d-glucose in 1–3 M KOH or NaOH (aqueous). Default (Table 1 Entry 1): 0.2 M RFP + 0.8 M glucose in 2 M NaOH. Catholyte (positive): 0.2–0.4 M K₃Fe(CN)₆ in 2 M KOH (aqueous). O₂ system: 1 M NaOH (middle chamber) |
| Temperature C | 25.0 |
| Active Material | Riboflavin 5′-phosphate sodium salt hydrate (RFP, Vitamin B₂, ≥95%, VWR) / d-glucose. Redox: RFP³⁻/RFP⁵⁻ (anode, E_a = −0.63 V vs SHE pH 14); Fe(CN)₆⁴⁻/Fe(CN)₆³⁻ (cathode, E_c = 0.48 V vs SHE pH 14) |
| Publication Doi | 10.1021/acsenergylett.5c02462 |
| Concentration Mm | 100.0 |
| Institution Code | ESRA |
| Potential Window | Full-cell voltage discharge low limit 0.75 V (not vs. reference electrode)Full-cell voltage discharge low limit 0.2-0.65 V (not vs. reference electrode) to ut-off voltage (discharge): 0.75 V (default); varied 0.45–1.2 V (cycling, Figure S5). OCV: ~1.1–1.25 V (depends on activation degree / SOC). Full-cell voltage (not vs. reference electrode) |
| Electrode Area Cm2 | 10.0 |
| Measurement Technique | LSV (linear sweep voltammetry) at 100 mV/s for polarization and power density curves (Gamry Potentiostat); constant current discharging and constant voltage discharging (Arbin battery testing system); OCV monitoring; UV-vis kinetics (SPECTRO star Nano, BMG Labtech, quartz cell 1 cm path length) |