Browse Data ESRA-CYC-0007 Cycling Public
⚠ Incomplete — 5 fields missing
Jin An Sam Oh
0000-0001-9336-234X
Ying Shirley Meng
Metastable Sodium Closo-Hydridoborates for All-Solid-State Batteries with Thick Cathodes
2025_JinAnSamOh_YingShirleyMeng_Joule_102130 ← click to see all uploads with this sample ID
10.1016/j.joule.2025.102130 ↗
2026-08-13 13:30:25
f16a9e94-1d20-4bdb-aa5d-a13ecf1ef323
How to Cite
1 — Cite the dataset paper
↗ View paper
2 — Cite the ESRA platform
Galib, M. et al. (2026). ESRA: Energy Storage Research Assistant. Argonne National Laboratory. https://github.com/MusannaGalib/esra-platform
CC BY 4.0  ·  Data shared under Creative Commons Attribution 4.0

Storage LocationNERSC Community File System

/global/cfs/cdirs/m4845/gsharing/ying-shirley-meng/metastable-sodium-closo-hydridoborates-f/2025-jinansamoh-yingshirleymeng-joule-10/Electrochemical/cycling/ESRA-CYC-0007/
Open in Globus File Manager →

Linked Uploads

Other datasets with the same sample ID (2025_JinAnSamOh_YingShirleyMeng_Joule_102130).

Type Group Date Project Link
XRD Ying Shirley Meng 2026-08-13 13:30 Metastable Sodium Closo-Hydridoborates for All-Solid-State Batteries with Thick Cathodes same sample
NMR Ying Shirley Meng 2026-08-13 13:30 Metastable Sodium Closo-Hydridoborates for All-Solid-State Batteries with Thick Cathodes same sample
MD Ying Shirley Meng 2026-08-13 13:30 Metastable Sodium Closo-Hydridoborates for All-Solid-State Batteries with Thick Cathodes same sample
EIS Ying Shirley Meng 2026-08-13 13:30 Metastable Sodium Closo-Hydridoborates for All-Solid-State Batteries with Thick Cathodes same sample
DFT Ying Shirley Meng 2026-08-13 13:30 Metastable Sodium Closo-Hydridoborates for All-Solid-State Batteries with Thick Cathodes same sample

Materials Studied 4 materials

Material Family Role(s) Ion
Metastable orthorhombic Na closo-hydridoborate (Na2B12H12 / Na2B10H10 / NaBH4 / NaB3H8)  · Sodium closo-hydridoborate SE
4.6 mS/cm at 30 C
Made in this work Material synthesis
  1. Vacuum dry — Dry Na2B12H12 precursor before synthesis
    duration: two nightsatmosphere: dynamic vacuumtemperature: 175 °C
    Main paper p. 8, Methods > Material synthesis
  2. Mix — Hand-mix stoichiometric Na2B12H12 and NaBH4 with pestle and mortar
    equipment: pestle and mortaratmosphere: Ar-filled gloveboxglovebox o2 ppm: 5glovebox h2o ppm: 5composition ratio: stoichiometric
    Main paper p. 8, Methods > Material synthesis
  3. Seal — Seal in thin-wall boron-rich capillary for in situ s-XRD OR evacuated quartz ampoule for bulk samples
    thickness: 0.01 mm (capillary wall)atmosphere: evacuated (bulk ampoule); sealed capillary (in situ s-XRD)
    Main paper p. 8, Methods > Material synthesis
  4. Heat
    duration: 10 htemperature: 410 °Cheating rate: 3 °C/min
    Main paper p. 8, Methods > Material synthesis
  5. Cool — Cool at either 0.5 or 2.0 °C/min depending on sample condition
    cooling rate: 0.5 and 2.0 °C/min
    Main paper p. 8, Methods > Material synthesis; SI cooling-rate comparison
  6. Quench — Rapid-cooling route: water quench for in situ s-XRD sample or transfer/quench in Ar-filled glovebox for bulk sample
    Main paper p. 8, Methods > Material synthesis
 Borohydride / complex hydride
Inorganic SE
 Electrolyte Na
Na9Sn4  · Na-Sn alloy anode
Made in this work Material synthesis
  1. Ball mill — Ball mill sodium metal with tin
    duration: 3 hequipment: Retsch EMAXatmosphere: Ar-filled gloveboxball diameter: 5 mmball material: yttrium-stabilized zirconiarotation speed: 500 rpmglovebox o2 ppm: 5glovebox h2o ppm: 5ball to powder ratio: 30:1
    Main paper p. 8, Methods > Material synthesis
 Alloy
Anode
 Anode Na
NaCrO2  · Layered sodium chromite cathode
Made in this work Material synthesis
  1. Mix — Pestle-and-mortar mix Na2CO3 and Cr2O3
    equipment: pestle and mortaratmosphere: Ar-filled gloveboxglovebox o2 ppm: <5glovebox h2o ppm: <5
    Main paper p. 8, Methods > Material synthesis
  2. Heat — Solid-state reaction
    duration: 10 hatmosphere: Artemperature: 900 °C
    Main paper p. 8, Methods > Material synthesis
 Layered oxide
Cathode
 Cathode Na
Hard carbon  · Hard-carbon anode Hard carbon
Anode
 Anode Na

Declared for sample 2025_JinAnSamOh_YingShirleyMeng_Joule_102130 — shared by every dataset on this sample.

Experiment Metadata

Visibility public
Temperature C 20.0
Anode Material Na₉Sn₄ alloy (Sn cast with PVDF 99:1; 35 mg Na₉Sn₄ or appropriate Sn amount; NP ratio 1.2–1.5 vs. NCO). Na metal used for symmetrical cell.
Publication Doi 10.1016/j.joule.2025.102130
Number Of Cycles 100 (half-cell Na₉Sn₄//o-NBH//NCO, Figure 4E); up to 1,000 (NCO/NZC full-cell, Figure 4E); 150 (comparative Figure 4E)
Cathode Material NaCrO₂ (NCO); composite: NCO:NZC:VGCF = 60:38:2 wt% or NCO:o-NBH:VGCF = 60:38:2 wt%; also NCO:NZC:o-NBH:VGCF = 60:20:18:2 wt%
Institution Code ESRA
Voltage Window — Lower 2.4
Voltage Window — Upper 3.4
Current / C-Rate / Protocol Summary C/10 (initial potential-capacity profiles); C/3 (capacity retention cycling); CCCV protocol: CC at C/3 then CV at 3.4 V until 0.1 C cutoff (1 C = 120 mAh g⁻¹). Symmetrical cell: 0.2 mA cm⁻², 5 h per half cycle.

Uploaded Files 10 files · 11.1 GB

Versions 0 saved

A version freezes the description and the list of files at one moment, so a paper can say which one it used. The ESRA ID stays the same. Saved automatically when a dataset is made public, and by hand below.

No version saved yet.